Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds

Authors
Otero Montero, Antonio; Royo Gracia, PascualUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4816
DOI: 10.1016/S0022-328X(00)82656-X
ISSN: 0022-328X
Publisher
Elsevier
Date
1979
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1979, v.171, n.3, p.333-336
Keywords
Arsenic
Antimony
Bismuth
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)82656-X
Rights
© Elsevier, 1979
Access rights
info:eu-repo/semantics/openAccess
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Abstract
(C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is rapidly hydrolysed to [(C6Cl5)2As]2O. Treatment of (C6Cl5)3Bi with halogens cleaves the C-Bi bonds to give C6Cl5X and unidentified oxohalobismuth(III) derivatives.
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