dc.contributor.author | Avilés, T. | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.date.accessioned | 2009-11-12T11:56:30Z | |
dc.date.available | 2009-11-12T11:56:30Z | |
dc.date.issued | 1981 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry,1981, v. 221, n. 3, p. 333-337 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4812 | |
dc.description.abstract | The reactions of [Co(η-C5H5)(PMe3)3][PF6]2 with the nucleophiles Y− = CN−, N3−, MeO−, H−, NO2− have been investigated. Only for Y− = CN− or N3− were crystalline products [Co(η-C5H5)(PMe3)2Y][PF6 (Y− = CN−, N3−) and Co(η-C5H5)(PMe3)(CN)2 isolated. MeO− and H− gave untractable products and with NO2− no reaction was observed. Reaction of Co(η-C5H5)(CO)I2 with PEt3 in the stoichiometry 1 : 1, 1 : 2 or 1 : 3 gave the complexes Co(η-C5H5)(PEt3)I2, [Co(η-C5H5)(PEt3)2I]I and a mixture of Co(PEt3)2(CO)2I and Co(PEt3)2I2, respectively. | en |
dc.description.sponsorship | Comisión Asesora de Investigación Científica y Técnica | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (c) Elsevier, 1981 | en |
dc.subject | Monocyclopentadienyl-cobalt cations | en |
dc.subject | Nucleophiles | en |
dc.title | Reactions of monocyclopentadienyl-cobalt cations with nucleophiles | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(00)88375-8 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(00)88375-8 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |