dc.contributor.author | Gómez Rubio, Manuel | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Sáez Sáez, Isabel María | |
dc.contributor.author | Arcas, Aurelia | |
dc.date.accessioned | 2009-11-12T11:31:10Z | |
dc.date.available | 2009-11-12T11:31:10Z | |
dc.date.issued | 1982 | |
dc.identifier.bibliographicCitation | Transition Metal Chemistry, 1982, v.7, n.6, p.294-297 | en |
dc.identifier.issn | 0340-4285 | |
dc.identifier.uri | http://hdl.handle.net/10017/4807 | |
dc.description.abstract | The reduction of nickel(II) halides with NaBH4 in the presence of different ligands, L=PPh3, AsPh3, SbPh3, has been studied. With a molar ratio L/Ni=3, new complexes NiX(SbPh3)3, X=Cl, Br, I, were obtained. With a molar ratio L/Ni=2, dimeric species [NiXL2]2, X=Cl, Br, I; L=PPh3, AsPh3, SbPh3, were isolated. They are unstable and decompose easily in the solid and rapidly in solution, so that pure samples were only identified for X=Cl, L=PPh3, AsPh3, SbPh3; X=Br, L=PPh3 and X=I, L=PPh3. With a molar ratio L/Ni=1, complexes [NiXL]n (probably polymeric) were obtained. They are very unstable and pure samples could only be isolated when X=Cl, L=PPh3. Impure substances containing variable amounts of decomposition products were obtained in all the remaining cases. The chemical and structural behaviour of these complexes is discussed. | en |
dc.description.sponsorship | Comisión Asesora de Investigación Científica y Técnica - CAICyT | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Springer Verlag | en |
dc.rights | © Springer, 1982 | en |
dc.subject | Halonickel(I) | en |
dc.title | Halonickel(I) complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1007/BF00618333 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1007/BF00618333 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |