View Item 
  •   e_Buah Home
  • INVESTIGACIÓN
  • DEPARTAMENTOS
  • Química Orgánica y Química Inorgánica
  • Unidad docente Química Inorgánica
  • QUIMINOR - Artículos
  • View Item
  • INVESTIGACIÓN
  • DEPARTAMENTOS
  • Química Orgánica y Química Inorgánica
  • Unidad docente Química Inorgánica
  • QUIMINOR - Artículos
  • View Item
  • Biblioteca
    • English
    • español
JavaScript is disabled for your browser. Some features of this site may not work without it.

Cyclopentadienylnickel complexes

Show full item record
RefworksUtilizar EndNote Import
Authors
Hernández Vizcaíno, Ma. Elisa; Royo Gracia, PascualUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4796
DOI: 10.1016/0022-328X(85)80190-X
ISSN: 0022-328X
Publisher
Elsevier
Date
1985
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1985, v.291, n.3, p.387-392
Keywords
Cyclopentadienylnickel
Project
2001-83 (Ministerio de Educación y Ciencia)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(85)80190-X
Rights
© Elsevier, 1985
Access rights
info:eu-repo/semantics/openAccess
Share
 
Abstract
The neutral complexes (η5-C5H5NiXL (X = Cl, L = PPh3 (I); L = PCy3 (II); X = Br, L = PPh3 (III); L = PCy3 (IV); X = I, L = PPh3 (V); L = PCy3 (VI)) have been obtained by treating NiX2L2 with thallium cyclopentadienide. The same reaction in the presence of TlBF4 gives cationic derivatives [(η5-C5H5)NiL2]BF4 (L = 2PPh2Me (VII); L = dppe (VIII)), whereas mononuclear complexes containing two different ligands (L2 = PPh3 + PCy3 (IX)) or dinuclear [(η5-C5H5)Ni(PPh3)]2dppe(BF4)2 (X) are obtained from the reaction of III with TlBF4 in the presence of a different ligand. Reduction of cationic complexes with Na/Hg gives very unstable nickel(I) derivatives (η5-C5H5)NiL2, which could not be isolated purely. Similar reduction of neutral complexes under CO gives a mixture of decomposition products containing [(η5-C5H5)Ni(CO)]2 and nickel(o) carbonyls, whereas in the presence of acetylenes, dinuclear [(η5-C5H5)Ni]2(RCCR′) (R = R′ = Ph; R = Ph, R′ = H) are obtained.
Files in this item
FilesSizeFormat
View
55.pdf191.8KbPDF
FilesSizeFormat
View
55.pdf191.8KbPDF
Collections
  • QUIMINOR - Artículos [186]

Contact Us | Send Feedback | About DSpace
¡CSS Válido!@mire NV
¡CSS Válido!@mire NV
 

 

Browse

All of e_BuahCommunities y CollectionsIssue DateAuthorsTitlesSubjectsIn this CollectionIssue DateAuthorsTitlesSubjects

My Account

My e_BuahCreate account

Help

What is e-Buah?Guide e_BuahGuide autoarchiveFAQContact us

Statistics

View Usage Statistics

Information

Open Science. Open accessOpen access PolicyPublishing permissionsCopyrightResearch datae-cienciaDatos RepositoryPlan de Gestión de Datos

Los contenidos se difunden en


Contact Us | Send Feedback | About DSpace
¡CSS Válido!@mire NV
¡CSS Válido!@mire NV