dc.contributor.author | Gómez Carrera, José Alberto | |
dc.contributor.author | Mena Montoro, Miguel | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Serrano Roche, Ricardo | |
dc.date.accessioned | 2009-11-12T09:43:51Z | |
dc.date.available | 2009-11-12T09:43:51Z | |
dc.date.issued | 1986 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1986, v.315, n.3, p.329-335 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4788 | |
dc.description.abstract | The chlorides MCl4 (M = Ti, Zr, Hf) react with the diols 4,4′-Me2C(C6H4OH)2 and 1,2-(OH)2Ar, Ar = C6H4, 4-MeC6H3, or 4-ButC6H3 to give the halogenoalkoxo derivatives MCl2(O2Ar). For M Ti these react with bases L (L = 2,2′-bipy, THF, Et2O) to give the corresponding adducts TiCl2(O2Ar)L, and with TlCp to give the monocyclopentadienyl complexes CpTiCl(O2Ar). The best way of preparing the analogous zirconium derivatives is through the reaction of CpZrCl3 · DME with (HO)2Ar. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1986 | |
dc.subject | Olefins | en |
dc.subject | Zirconium derivatives | en |
dc.title | Halo(alkoxo) and monocyclopentadienyl(halo)alkoxo derivatives of titanium, zirconium and hafnium | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | |
dc.subject.eciencia | Química inorgánica | |
dc.subject.eciencia | Science | |
dc.subject.eciencia | Chemistry, inorganic | |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(86)80453-3 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(86)80453-3 | |
dc.relation.projectID | R0407/84 (Ministerio de Educación y Ciencia) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |