| dc.contributor.author | Avilés, T. | |
| dc.contributor.author | Barroso Parla, Francisca | |
| dc.contributor.author | Royo Gracia, Pascual | |
| dc.date.accessioned | 2009-11-06T11:41:08Z | |
| dc.date.available | 2009-11-06T11:41:08Z | |
| dc.date.issued | 1987 | |
| dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1987, v. 326, p. 423-429 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/10017/4664 | |
| dc.description.abstract | The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands gives new cobalt complexes containing cations [Co(η3-2-MeC3H4)(η5-C5H5)L]n+, n = 0; L = CN, CH3COO, CF3COO and n = 1; L = P(p-MePh)3, NCEt, NCPh, CNCy, dppm and [{Co(η3-2-MeC3H4)(η5-C5H5)}2 (μ-L-L)]2+, L-L = bipy, dppm. The neutral cyano complex reacts with various electrophiles to give cationic isocyanide complexes containing the cation [Co(η3-2-MeC3H4)(η5-C5H5)(CNR)]+, which have been isolated in low yields. Chemical behaviour and structural implications of IR and 1H and 13C NMR spectra are discussed. | en |
| dc.description.sponsorship | The authors greatly appreciate financial support from the Comisión Asesora de Investigación Científica y Técnica. Ref. 2001/83. Spain. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | (c) Elsevier, 1987 | en |
| dc.subject | Cyclopentadienylcobalt complexes | en |
| dc.title | New neutral and cationic cyclopentadienylcobalt complexes | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, inorganic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(87)87014-6 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/0022-328X(87)87014-6 | |
| dc.relation.projectID | 2001/83 (Ministerio de Educación y Ciencia) | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
