New neutral and cationic cyclopentadienylcobalt complexes

Authors
Avilés, T.; Barroso Parla, Francisca; Royo Gracia, PascualUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4664
DOI: 10.1016/0022-328X(87)87014-6
ISSN: 0022-328X
Publisher
Elsevier
Date
1987
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Funders
The authors greatly appreciate financial support from the Comisión Asesora de Investigación Científica y Técnica. Ref. 2001/83. Spain.
Bibliographic citation
Journal of Organometallic Chemistry, 1987, v. 326, p. 423-429
Keywords
Cyclopentadienylcobalt complexes
Project
2001/83 (Ministerio de Educación y Ciencia)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(87)87014-6
Rights
(c) Elsevier, 1987
Access rights
info:eu-repo/semantics/openAccess
Share
 
Abstract
The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands gives new cobalt complexes containing cations [Co(η3-2-MeC3H4)(η5-C5H5)L]n+, n = 0; L = CN, CH3COO, CF3COO and n = 1; L = P(p-MePh)3, NCEt, NCPh, CNCy, dppm and [{Co(η3-2-MeC3H4)(η5-C5H5)}2 (μ-L-L)]2+, L-L = bipy, dppm. The neutral cyano complex reacts with various electrophiles to give cationic isocyanide complexes containing the cation [Co(η3-2-MeC3H4)(η5-C5H5)(CNR)]+, which have been isolated in low yields. Chemical behaviour and structural implications of IR and 1H and 13C NMR spectra are discussed.
Files in this item
Collections