New neutral and cationic cyclopentadienylcobalt complexes

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Authors
Avilés, T.; Barroso Parla, Francisca; Royo Gracia, PascualUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4664
DOI: 10.1016/0022-328X(87)87014-6
ISSN: 0022-328X
Publisher
Elsevier
Date
1987
Academic Departments
Universidad de Alcalá. Departamento de Química Inorgánica
Teaching unit
Unidad docente Química Inorgánica
Funders
The authors greatly appreciate financial support from the Comisión Asesora de Investigación Científica y Técnica. Ref. 2001/83. Spain.
Ministerio de Educación y Ciencia
Bibliographic citation
Journal of Organometallic Chemistry, 1987, v. 326, p. 423-429
Keywords
Cyclopentadienylcobalt complexes
Project
info:eu-repo/grantAgreement/MEC//2001-83/ES
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(87)87014-6
Rights
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Access rights
info:eu-repo/semantics/openAccess
Abstract
The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands gives new cobalt complexes containing cations [Co(η3-2-MeC3H4)(η5-C5H5)L]n+, n = 0; L = CN, CH3COO, CF3COO and n = 1; L = P(p-MePh)3, NCEt, NCPh, CNCy, dppm and [{Co(η3-2-MeC3H4)(η5-C5H5)}2 (μ-L-L)]2+, L-L = bipy, dppm. The neutral cyano complex reacts with various electrophiles to give cationic isocyanide complexes containing the cation [Co(η3-2-MeC3H4)(η5-C5H5)(CNR)]+, which have been isolated in low yields. Chemical behaviour and structural implications of IR and 1H and 13C NMR spectra are discussed.

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