Show simple item record

dc.contributor.authorGómez Sal, Pilar
dc.contributor.authorJesús Alcañiz, Ernesto de 
dc.contributor.authorRoyo Gracia, Pascual 
dc.contributor.authorVázquez de Miguel, Amelio 
dc.date.accessioned2009-11-06T11:00:55Z
dc.date.available2009-11-06T11:00:55Z
dc.date.issued1988
dc.identifier.bibliographicCitationJournal of Organometallic Chemistry, 1988, v. 353, p. 191-196en
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10017/4650
dc.description.abstractReaction of [Mo{η5-C5(CH3)5}(Br)(CH3)(NO)]2 (I) with air in sunlight gives a mixture of two oxo complexes: [Mo{C5(CH3)5}(Br)(O)2] (III) and [Mo{η5-C5(CH3)5}(O)2](μ-O))) (IV). The X-ray structure of IV shows a space group P21/a, with a 17.660(1), b 9.238(1), c 21.277(1) Å, β 101.79(1)°, and Dcal 1.590 g cm−3 for Z = 6. A final R value of 0.064 (Rw = 0.064), based on 3300 observed reflections was obtained. The dimeric molecule can be regarded as made up of two distorted tetrahedra which share a common oxygen atom. The asymmetric unit in the unit cell contains 1.5 dimeric molecules.en
dc.description.sponsorshipThe authors acknowledge financial support from the Comisión Asesora de Investigación Científica y Técnica. Ref. 2001-83en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.rights(c) Elsevier, 1988en
dc.subjectAir-decomposition of [Mo(μ-Br)(C5(CH3)5)(CH3)(NO)]2en
dc.subjectCrystal structure of [Mo(C5(CH3)5)(O)2](μ-O)en
dc.titleAir-decomposition of [Mo(μ-Br)(C5(CH3)5)(CH3)(NO)]2; Crystal structure of [Mo(C5(CH3)5)(O)2](μ-O)en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCIENCIAes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaSCIENCEen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1016/0022-328X(88)83063-8
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/0022-328X(88)83063-8
dc.relation.projectID2001-83 (Comisión Asesora de Investigación Científica y Técnica)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


Files in this item

Thumbnail

This item appears in the following Collection(s)