Structural and chemical aspects of electron deficient pentamethylcyclopentadienyltitanium halides, alkyls, and oxides

Authors
Gómez Sal, Pilar; Mena Montoro, MiguelUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; Serrano Roche, Ricardo
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4649
DOI: 10.1016/0022-328X(88)87076-1
ISSN: 0022-328X
Publisher
Elsevier
Date
1988
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Funders
The research described here is included in Project PR-84-0407 financially sup­ ported by CAICYT and sponsored by Repsol Petr6leo. We are also indebted to S. Martinez Carreras and S. Garcia Blanco of the Departamento de Cristalografia CSIC (Madrid), and to Prof. A. Tiripicchio of the Centro di Studio per la Strutturistica Diffrattometrica de!CNR de la Universita di Parma (Italy) for determination of the X-ray structures. Our excellent co-workers J.C. Flores, F. Palacios and Dra. I. Saez carried out some of the experimental work described here and their collaboration is warmly acknowledged.
Bibliographic citation
Journal of Organometallic Chemistry, 1988, v. 358, p. 147-159
Keywords
Pentamethylcyclopentadienyltitanium halides
Alkyls
Oxides
Project
PR-84-0407 (Ministerio de Educación y Ciencia)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(88)87076-1
Rights
(c) Elsevier, 1988
Access rights
info:eu-repo/semantics/openAccess
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Abstract
We were interested in electron deficient organotitanium complexes das potential Ziegler-Natta catalysts likely to show particularly interesting structural features and easily accessible low valent oxidation states and so we chose pentamethylcyclopentadienyltitanium trichloride as the starting product for our studies
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