| dc.contributor.author | Gómez Rubio, Manuel | |
| dc.contributor.author | Martínez de Ilarduya, Jesús María | |
| dc.contributor.author | Royo Gracia, Pascual | |
| dc.date.accessioned | 2009-11-06T10:43:08Z | |
| dc.date.available | 2009-11-06T10:43:08Z | |
| dc.date.issued | 1989 | |
| dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1989, v. 369, n. 2, p. 197-204 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/10017/4645 | |
| dc.description.abstract | New dicyclopentadienylniobium(III) complexes have been made by reducing NbCp2Cl2 (Cp = η5-C5H5, η5-C5H4SiMe3 and η5-C5H3(SiMe3)2) with Na/Hg in the presence of isocyanides CNR (R = Bun, But, Ph and 2,6-Me2C6H3). These compounds are readily oxidized by AgBF4, to give the corresponding niobium(IV) cations [NbCp2ClL]+, by O2 to give peroxoniobium(V) derivatives NbCp2Cl(η2-O2), and by t-butyl hydroperoxide to give the known oxo derivatives NbCp2Cl(O), which can also be made by oxygen transfer from the peroxo compound to triphenylphosphine. | en |
| dc.format.mimetype | application/pdf | en |
| dc.language.iso | eng | en |
| dc.publisher | Elsevier | en |
| dc.rights | (c) Elsevier, 1989 | en |
| dc.subject | Niobium(III) isocyanide complexes | en |
| dc.subject | Oxidizing reagents | en |
| dc.title | Reactions of metallocene niobium(III) isocyanide complexes with oxidizing reagents | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.subject.eciencia | Ciencia | es_ES |
| dc.subject.eciencia | Química inorgánica | es_ES |
| dc.subject.eciencia | Science | en |
| dc.subject.eciencia | Chemistry, inorganic | en |
| dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
| dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(89)88007-6 | |
| dc.type.version | info:eu-repo/semantics/publishedVersion | en |
| dc.identifier.doi | 10.1016/0022-328X(89)88007-6 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |
