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dc.contributor.authorPalacios Gragera, Federico Fernando 
dc.contributor.authorRoyo Gracia, Pascual 
dc.contributor.authorSerrano Roche, Ricardo
dc.contributor.authorBalcázar del Piñal, José Luis
dc.contributor.authorFonseca, I.
dc.contributor.authorFlorencio Sabaté, Feliciana
dc.date.accessioned2009-11-06T09:35:48Z
dc.date.available2009-11-06T09:35:48Z
dc.date.issued1989
dc.identifier.bibliographicCitationJournal of Organometallic Chemistry, 1989, v.375, n.1, p.51-58en
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10017/4643
dc.description.abstractControlled hydrolysis of pentamethylcyclopentadienyltitanium trihalides Cp★TiX3 in toluene in the presence of NHEt2 leads to the isolation of compounds of the types [Cp★TiX2]2(μ-O) (X = Cl, Br, I), [Cp★TiX(μ-O)]n (X = Cl, n = 3; X = Br, n = 4] and finally [Cp★Ti]4(μ-O)6 depending upon the Ti/H2O stoichiometry. The crystal structure of [Cp★TiBr(μ-O)]4 has been determined: the compound crystallizes with one molecule of CHCl3 in the orthorhombic space group Pnca and contains a Ti4O4 ring of alternating Ti and O atoms. The four oxygen atoms lie in a plane, with the titanium atoms situated alternately ± 0.191(2) Å above and below this plane.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.rights© Elsevier, 1989en
dc.subjectCrystal structureen
dc.subjectPentamethylcyclopentadienyltitaniumen
dc.titleThe hydrolysis of pentamethylcyclopentadienyltitanium trihalides and the formation of di-nuclear, tri-nuclear, and tetra-nuclear µ-oxo complexes. Crystal structure of [(C5Me5)TiBr(µ-O)]4CHCL3, which contains a Ti4O4 ringen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCienciaes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaScienceen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1016/0022-328X(89)85083-1
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/0022-328X(89)85083-1
dc.relation.projectIDPB87-0756 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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