dc.contributor.author | Palacios Gragera, Federico Fernando | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Serrano Roche, Ricardo | |
dc.contributor.author | Balcázar del Piñal, José Luis | |
dc.contributor.author | Fonseca, I. | |
dc.contributor.author | Florencio Sabaté, Feliciana | |
dc.date.accessioned | 2009-11-06T09:35:48Z | |
dc.date.available | 2009-11-06T09:35:48Z | |
dc.date.issued | 1989 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1989, v.375, n.1, p.51-58 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4643 | |
dc.description.abstract | Controlled hydrolysis of pentamethylcyclopentadienyltitanium trihalides Cp★TiX3 in toluene in the presence of NHEt2 leads to the isolation of compounds of the types [Cp★TiX2]2(μ-O) (X = Cl, Br, I), [Cp★TiX(μ-O)]n (X = Cl, n = 3; X = Br, n = 4] and finally [Cp★Ti]4(μ-O)6 depending upon the Ti/H2O stoichiometry. The crystal structure of [Cp★TiBr(μ-O)]4 has been determined: the compound crystallizes with one molecule of CHCl3 in the orthorhombic space group Pnca and contains a Ti4O4 ring of alternating Ti and O atoms. The four oxygen atoms lie in a plane, with the titanium atoms situated alternately ± 0.191(2) Å above and below this plane. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1989 | en |
dc.subject | Crystal structure | en |
dc.subject | Pentamethylcyclopentadienyltitanium | en |
dc.title | The hydrolysis of pentamethylcyclopentadienyltitanium trihalides and the formation of di-nuclear, tri-nuclear, and tetra-nuclear µ-oxo complexes. Crystal structure of [(C5Me5)TiBr(µ-O)]4CHCL3, which contains a Ti4O4 ring | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(89)85083-1 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(89)85083-1 | |
dc.relation.projectID | PB87-0756 (Comisión Interministerial de Ciencia y Tecnología-CICYT) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |