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The hydrolysis of pentamethylcyclopentadienyltitanium trihalides and the formation of di-nuclear, tri-nuclear, and tetra-nuclear µ-oxo complexes. Crystal structure of [(C5Me5)TiBr(µ-O)]4CHCL3, which contains a Ti4O4 ring

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Authors
Palacios Gragera, Federico FernandoUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; Serrano Roche, Ricardo; Balcázar del Piñal, José Luis; Fonseca, I.; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4643
DOI: 10.1016/0022-328X(89)85083-1
ISSN: 0022-328X
Publisher
Elsevier
Date
1989
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 1989, v.375, n.1, p.51-58
Keywords
Crystal structure
Pentamethylcyclopentadienyltitanium
Project
PB87-0756 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(89)85083-1
Rights
© Elsevier, 1989
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Controlled hydrolysis of pentamethylcyclopentadienyltitanium trihalides Cp★TiX3 in toluene in the presence of NHEt2 leads to the isolation of compounds of the types [Cp★TiX2]2(μ-O) (X = Cl, Br, I), [Cp★TiX(μ-O)]n (X = Cl, n = 3; X = Br, n = 4] and finally [Cp★Ti]4(μ-O)6 depending upon the Ti/H2O stoichiometry. The crystal structure of [Cp★TiBr(μ-O)]4 has been determined: the compound crystallizes with one molecule of CHCl3 in the orthorhombic space group Pnca and contains a Ti4O4 ring of alternating Ti and O atoms. The four oxygen atoms lie in a plane, with the titanium atoms situated alternately ± 0.191(2) Å above and below this plane.
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