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dc.contributor.authorGómez Ramírez, Rafael 
dc.contributor.authorCuenca Agreda, Tomás
dc.contributor.authorRoyo Gracia, Pascual 
dc.contributor.authorHerrmann, Wolfgang A.
dc.contributor.authorHerdtweck, Eberhardt
dc.date.accessioned2009-11-06T09:12:18Z
dc.date.available2009-11-06T09:12:18Z
dc.date.issued1990
dc.identifier.bibliographicCitationJournal of Organometallic Chemistry, 1990, v.382, n.1-2, p.103-108en
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10017/4636
dc.description.abstractReaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes [(η5-C5H4)2Si(CH3)2]MCl2 (M = Ti (1) and Zr (2). Along with the predominant product in each case a new titanium and zirconium compound is isolated. Treatment of the complexes 1 and 2 with LiCH2Si(CH3)3 gives the novel derivatives [(η5-C5H4)2Si(CH3)2]M[CH2Si(CH3)3]2 (M = Ti (4) and Zr (5)) which have been characterized by NMR and mass spectrometry and in the case of 4 by an X-ray structural determination.en
dc.description.sponsorshipDeustche Akademische Austauschdiensten
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.rights© Elsevier, 1990en
dc.subjectTitaniumen
dc.subjectZirconiumen
dc.subjectCrystal structureen
dc.titleStereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCIENCIAes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaSCIENCEen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1016/0022-328X(90)85219-O
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/0022-328X(90)85219-O
dc.relation.projectIDPB86-0093 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
dc.relation.projectIDMEC-DAAD No. 1/51 B (Ministerio de Educación y Ciencia)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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