dc.contributor.author | Gómez Ramírez, Rafael | |
dc.contributor.author | Cuenca Agreda, Tomás | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Herrmann, Wolfgang A. | |
dc.contributor.author | Herdtweck, Eberhardt | |
dc.date.accessioned | 2009-11-06T09:12:18Z | |
dc.date.available | 2009-11-06T09:12:18Z | |
dc.date.issued | 1990 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1990, v.382, n.1-2, p.103-108 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4636 | |
dc.description.abstract | Reaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes [(η5-C5H4)2Si(CH3)2]MCl2 (M = Ti (1) and Zr (2). Along with the predominant product in each case a new titanium and zirconium compound is isolated. Treatment of the complexes 1 and 2 with LiCH2Si(CH3)3 gives the novel derivatives [(η5-C5H4)2Si(CH3)2]M[CH2Si(CH3)3]2 (M = Ti (4) and Zr (5)) which have been characterized by NMR and mass spectrometry and in the case of 4 by an X-ray structural determination. | en |
dc.description.sponsorship | Deustche Akademische Austauschdienst | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1990 | en |
dc.subject | Titanium | en |
dc.subject | Zirconium | en |
dc.subject | Crystal structure | en |
dc.title | Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2 | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(90)85219-O | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(90)85219-O | |
dc.relation.projectID | PB86-0093 (Comisión Interministerial de Ciencia y Tecnología-CICYT) | |
dc.relation.projectID | MEC-DAAD No. 1/51 B (Ministerio de Educación y Ciencia) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |