The molecular structure of Me3TiCp* in the gas phase

Autores
Blom, R.; Rypdal, K.; Mena Montoro, MiguelAutor Universidad de Alcalá; Royo Gracia, PascualAutor Universidad de Alcalá; Serrano Roche, Ricardo
Identificadores
Enlace permanente (URI): http://hdl.handle.net/10017/4633
DOI: 10.1016/0022-328X(90)80155-S
ISSN: 0022-328X
Editor
Elsevier
Fecha de publicación
1990
Filiación
Universidad de Alcalá. Departamento de Química Inorgánica
Patrocinadores
Norwegian Research Council for Science and Humanities
VISTA program
Cita bibliográfica
Journal of Organometallic Chemistry, 1990, v.391, n.1, p.47-51
Palabras clave
Gas phase electron diffraction
GED
Methyl groups
Tipo de documento
info:eu-repo/semantics/article
Versión
info:eu-repo/semantics/publishedVersion
Versión del editor
http://dx.doi.org/10.1016/0022-328X(90)80155-S
Derechos
© Elsevier, 1990
Derechos de acceso
info:eu-repo/semantics/openAccess
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Resumen
The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm.
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