The molecular structure of Me3TiCp* in the gas phase
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4633DOI: 10.1016/0022-328X(90)80155-S
ISSN: 0022-328X
Publisher
Elsevier
Date
1990Funders
Norwegian Research Council for Science and Humanities
VISTA program
Bibliographic citation
Journal of Organometallic Chemistry, 1990, v.391, n.1, p.47-51
Keywords
Gas phase electron diffraction
GED
Methyl groups
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(90)80155-SRights
© Elsevier, 1990
Access rights
info:eu-repo/semantics/openAccess
Abstract
The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm.
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