The molecular structure of Me3TiCp* in the gas phase

Authors
Blom, R.; Rypdal, K.; Mena Montoro, MiguelUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; Serrano Roche, Ricardo
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4633
DOI: 10.1016/0022-328X(90)80155-S
ISSN: 0022-328X
Publisher
Elsevier
Date
1990
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Funders
Norwegian Research Council for Science and Humanities
VISTA program
Bibliographic citation
Journal of Organometallic Chemistry, 1990, v.391, n.1, p.47-51
Keywords
Gas phase electron diffraction
GED
Methyl groups
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0022-328X(90)80155-S
Rights
© Elsevier, 1990
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm.
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