dc.contributor.author | Gómez Rubio, Manuel | |
dc.contributor.author | Jiménez Pindado, Gerardo | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Pellinghelli, Maria Angela | |
dc.contributor.author | Tiripicchio, Antonio | |
dc.date.accessioned | 2009-11-06T08:39:59Z | |
dc.date.available | 2009-11-06T08:39:59Z | |
dc.date.issued | 1992 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1992, v. 439, p. 309-318 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4628 | |
dc.description.abstract | The X-ray diffraction study of [TaCp★Cl3{(CH2)2PPh2}] confirms its monomeric structure, previously proposed on the basis of its NMR behaviour. Alkylation of this compound leads to the isolation of its trimethyl derivative, along with a residue which contains minor amounts of the monomethyl complex. The pyrolysis of the trimethyl complex affords [TaCp★Me2{(CH)(CH2)PPh2}] whose crystal structure has been determined by X-ray diffraction methods. | en |
dc.description.sponsorship | We thank CICYT (Grant No PB89-0208), CEE (SCl*/0137-C AM), C.N.R.
(Rome) and Italian Ministero dell'Università e della Ricerca Scientifica e Tecno logica (MURST) for financial support for this research. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (c) Elsevier, 1992 | en |
dc.subject | Molecular structure | en |
dc.subject | Complexes | en |
dc.subject | Tantalum | en |
dc.title | Methylation of (pentamethylcyclopentadienyl)trichloro(diphenyldimethylenephosphoranyl-C,C)tantalum(V). Crystal structures of [TaCp*Cl3((CH2)2PPh2)] and [TaCp*Me2((CH)(CH2)PPh2)] | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(92)85095-E | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(92)85095-E | |
dc.relation.projectID | PB89-0208 (Comisión Interministerial de Ciencia y Tecnología-CICYT) | |
dc.relation.projectID | Info:eu-repo/SCl*/0137-C AM | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |