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dc.contributor.authorGómez Rubio, Manuel 
dc.contributor.authorGómez Sal, Pilar
dc.contributor.authorNicolás Utrilla, María Pilar
dc.contributor.authorRoyo Gracia, Pascual 
dc.date.accessioned2009-11-04T10:44:50Z
dc.date.available2009-11-04T10:44:50Z
dc.date.issued1995
dc.identifier.bibliographicCitationJournal of Organometallic Chemistry, 1995, v.491, n.1-2, p.121-125en
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10017/4589
dc.description.abstract[TaCp★Cl4](Cp★ = η5-C5Me5) reacts with isocyanides and amines to give the pseudo-octahedral adducts [TaCp★Cl4L] (L = 2,6-Me2C6H3NC, 1; 2,4,6-Me3C6H2NC, 2; tBuNC, 3; or C6H5NH2, 4). Reduction of 1, or alternatively of [TaCp★Cl4] in the presence of stoichiometric amounts of isocyanide, with two equivalents of Na/Hg gives the diamagnetic pseudo-octahedral tantalum(III) complex, [TaCp★Cl2(CN-2,6-Me2C6H3)35. Reaction of 4 with two equivalents of LiNEt2 affords the pseudo-octahedral imido complex [TaCp★Cl2(NC6H5). 6. All the complexes were characterized by usual IR and NMR spectroscopic methods and the molecular structure of I was confirmed by X-ray diffraction methods.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.rights© Elsevier, 1995en
dc.subjectTantalumen
dc.subjectPentamethylcyclopentadienylen
dc.subjectIsonitrile complexesen
dc.subjectX-ray diffractionen
dc.subjectAmine complexesen
dc.subjectImido complexesen
dc.titleMonopentamethylcyclopentadienyl isocyanide, amine and imido tantalum(V) complexes. X-ray crystal structure of [TaCp*Cl4(CN-2,6-Me2C6H3)]en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCienciaes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaScienceen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1016/0022-328X(94)05236-5
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/0022-328X(94)05236-5
dc.relation.projectIDPB-92-0178-C (Ministerio de Educación y Ciencia)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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