dc.contributor.author | Gómez Rubio, Manuel | |
dc.contributor.author | Gómez Sal, Pilar | |
dc.contributor.author | Nicolás Utrilla, María Pilar | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.date.accessioned | 2009-11-04T10:44:50Z | |
dc.date.available | 2009-11-04T10:44:50Z | |
dc.date.issued | 1995 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1995, v.491, n.1-2, p.121-125 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4589 | |
dc.description.abstract | [TaCp★Cl4](Cp★ = η5-C5Me5) reacts with isocyanides and amines to give the pseudo-octahedral adducts [TaCp★Cl4L] (L = 2,6-Me2C6H3NC, 1; 2,4,6-Me3C6H2NC, 2; tBuNC, 3; or C6H5NH2, 4). Reduction of 1, or alternatively of [TaCp★Cl4] in the presence of stoichiometric amounts of isocyanide, with two equivalents of Na/Hg gives the diamagnetic pseudo-octahedral tantalum(III) complex, [TaCp★Cl2(CN-2,6-Me2C6H3)35. Reaction of 4 with two equivalents of LiNEt2 affords the pseudo-octahedral imido complex [TaCp★Cl2(NC6H5). 6. All the complexes were characterized by usual IR and NMR spectroscopic methods and the molecular structure of I was confirmed by X-ray diffraction methods. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1995 | en |
dc.subject | Tantalum | en |
dc.subject | Pentamethylcyclopentadienyl | en |
dc.subject | Isonitrile complexes | en |
dc.subject | X-ray diffraction | en |
dc.subject | Amine complexes | en |
dc.subject | Imido complexes | en |
dc.title | Monopentamethylcyclopentadienyl isocyanide, amine and imido tantalum(V) complexes. X-ray crystal structure of [TaCp*Cl4(CN-2,6-Me2C6H3)] | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0022-328X(94)05236-5 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0022-328X(94)05236-5 | |
dc.relation.projectID | PB-92-0178-C (Ministerio de Educación y Ciencia) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |