Show simple item record

C−H Functionalization of BN-Aromatics Promoted by Addition of Organolithium Compounds to the Boron Atom

dc.contributor.authorAbengózar Muñoz, Alberto 
dc.contributor.authorFernández González, Miguel Ángel 
dc.contributor.authorSucunza Sáenz, David 
dc.contributor.authorFrutos Gaite, Luis Manuel 
dc.contributor.authorSalgado Serrano, Antonio 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorVaquero López, Juan J.
dc.date.accessioned2020-07-15T13:37:36Z
dc.date.available2020-07-15T13:37:36Z
dc.date.issued2018-08-17
dc.identifier.bibliographicCitationOrganic Letters, 2018, v. 20, n. 16, p. 4902-4906en
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10017/43801en
dc.description.abstractAddition of an organolithium compound to a BN-phenanthrene with embedded B and N atoms is proposed to result in coordination of RLi to the boron atom. This coordination, supported by NMR spectroscopy and DFT calculations, increases the nucleophilicity of the system in the b position to the N atom, and is therefore a useful tool for promoting regioselective C-H functionalization of BN aromaticsen
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© 2018 American Chemical Societyen
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectBN-phenanthreneen
dc.subjectC-H functionalizationen
dc.subjectorganolithium compounden
dc.subjectNMRen
dc.subjectDFTen
dc.titleC−H Functionalization of BN-Aromatics Promoted by Addition of Organolithium Compounds to the Boron Atomen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Químicaes_ES
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánicaes_ES
dc.date.updated2020-07-15T13:36:55Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/acs.orglett.8b02040en
dc.relation.projectIDCTQ2014-52488-R, CTQ2016-80600-P, CTQ2017-85263-R (Ministerio de Economía y Competitividad, AEI and FEDER); RETIC REDINREN RD16/0009/0015 (Instituto de Salud Carlos III, FEDER); CCGP2017-EXP012 (University of Alcalá)es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000028680
dc.identifier.publicationtitleOrganic Lettersen
dc.identifier.publicationvolume20
dc.identifier.publicationlastpage4906
dc.identifier.publicationissue16
dc.identifier.publicationfirstpage4902


Files in this item

Thumbnail
Name:
Functionalization_Abengozar_Or ...
Size:
797.0Kb
Format:
PDF
View/Open

This item appears in the following Collection(s)

Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
Este ítem está sujeto a una licencia Creative Commons.