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dc.contributor.authorGarre Hernández, María Soledad
dc.contributor.authorSucunza Sáenz, David
dc.contributor.authorAguilar, Enrique
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorVaquero López, Juan J.
dc.date.accessioned2020-07-15T10:10:39Z
dc.date.available2020-07-15T10:10:39Z
dc.date.issued2019-05-03
dc.identifier.bibliographicCitationThe Journal of Organic Chemistry, 2019, v. 84, n. 9, p. 5712-5725en
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/10017/43792en
dc.description.abstractCyclobutane-fused dihydropyrans and methylenetetrahydrofurans are highly interesting cores found in numerous natural products. Both these cores are selectively prepared from a common alkynylcyclobutane precursor bearing an appended hydroxyl group herein. Thus, cyclobutane-fused dihydropyrans can be obtained by a selective 6-endo-dig iodocyclization, whereas gold-catalyzed 5-exo-dig cycloisomerization provides a bicyclic core containing a methylenetetrahydrofuran moiety as major product. Several cyclobutane-fused O-heterocycles with diverse substituents are synthesized following the reported methodologyen
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© 2019 American Chemical Societyen
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectCyclobutaneen
dc.subjectdihydropyranen
dc.subjectmethylenetetrahydrofuranen
dc.subjectgolden
dc.subjectiodineen
dc.subjectelectrophilic cyclizationen
dc.titleRegiodivergent Electrophilic Cyclizations of Alkynylcyclobutanes for the Synthesis of Cyclobutane-Fused O-Heterocyclesen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánicaes_ES
dc.date.updated2020-07-15T10:10:11Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/acs.joc.9b00618en
dc.relation.projectIDCTQ2014-52488-R, CTQ2017-85263-R (Ministerio de Economía y Competitividad, AEI, FEDER); RETIC REDINREN RD16/0009/0015 (Instituto de Salud Carlos III, FEDER); CCG2015/EXP-003 (University of Alcalá)es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000030575en
dc.identifier.publicationtitleThe Journal of Organic Chemistryen
dc.identifier.publicationvolume84
dc.identifier.publicationlastpage5725
dc.identifier.publicationissue9
dc.identifier.publicationfirstpage5712


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