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Practical solvent-free microwave-assisted hydroboration of alkynes

dc.contributor.authorAltarejos Salido, Julia 
dc.contributor.authorSucunza Sáenz, David 
dc.contributor.authorVaquero López, Juan J.
dc.contributor.authorCarreras Pérez Aradros, Javier 
dc.date.accessioned2020-06-24T10:54:38Z
dc.date.issued2020-04-16
dc.identifier.bibliographicCitationEuropean Journal of Organic Chemistry, 2020, v. 2020, n. 20, p. 3024-3029en
dc.identifier.issn1434-193X
dc.identifier.urihttp://hdl.handle.net/10017/43407en
dc.description.abstractA simple and rapid protocol for the anti-Markovnikov hydroboration of alkynes assisted by microwave irradiation has been developed. Pinacolborane smoothly reacts with terminal alkynes to obtain (E)-alkenyl boronates in good yields and short reactions times in the absence of solvent. Further transformations on the carbon-boron bond of the adducts can be sequentially achieved without the need of purifying the alkenyl boronates.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© Wiley, 2020en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectAlkynesen
dc.subjectHydroborationen
dc.subjectMicrowave chemistryen
dc.subjectAlkenyl boronatesen
dc.subjectSolvent-free synthesisen
dc.titlePractical solvent-free microwave-assisted hydroboration of alkynesen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánicaes_ES
dc.date.updated2020-06-24T10:47:56Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1002/ejoc.202000110en
dc.relation.projectIDCTQ2017-85263-R (Ministerio de Economía y Competitividad); RD16/0009/0015 (RETIC REDinREN, Instituto de Salud Carlos III); CM/JIN/2019-025 (Comunidad de Madrid y Universidad de Alcalá); CCG19/CC-038 (Universidad de Alcalá)es_ES
dc.date.embargoEndDate2021-04-16
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000033399en
dc.identifier.publicationtitleEuropean Journal of Organic Chemistryen
dc.identifier.publicationvolume2020
dc.identifier.publicationlastpage3029
dc.identifier.publicationissue20
dc.identifier.publicationfirstpage3024


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