dc.contributor.author | Royo Cantabrana, Beatriz | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Cadenas Rodríguez, Luis Manuel | |
dc.date.accessioned | 2009-10-20T13:11:28Z | |
dc.date.available | 2009-10-20T13:11:28Z | |
dc.date.issued | 1998 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1998, v. 551, p. 293-297 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4279 | |
dc.description.abstract | The synthesis of (C5H4)(SiMeCl2)(SiMe3) is described. The reaction of a dichloromethane solution of this compound with one equivalent of titanium tetrachloride leads to the monocyclopentadienyl complex [TiCl3{η5-C5H4(SiMeCl2)}]. Treatment of this complex with the lithium amides LiN(SiMe3)2 and LiNHtBu affords [TiCl2{N(SiMe3)2}{η5-C5H4(SiMeCl2)}] and [TiCl2{η5-C5H4[SiMeCl(η-NtBu)]}], respectively. Alkylation of the trichlorotitanium derivative with 1.5 equivalents of Mg(CH2C6H5)2(THF)2 leads to the tribenzyl derivative [Ti(CH2C6H5)3{η5-C5H4(SiMeCl2)}]. Hydrolysis of the trichloro- and tribenzyl-complexes leads to the μ-oxo dititanium compounds [TiX2μ-{η5-C5H4(η-OSiMeCl)}]2 (X=Cl, CH2Ph). All of the new complexes were characterized by elemental analysis and NMR spectroscopy. | en |
dc.description.sponsorship | We are grateful to the DGICYT (Project PB-92-0178-C) and CAM (I + D 0034/94) for financial support.
B.R. acknowledges Universidad de Alcalá de Henares for support provided (Project 042/95) | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (c) Elsevier, 1998 | en |
dc.subject | Titanium | en |
dc.subject | wDichloro methyl.silylxcyclopentadienyl | en |
dc.subject | Amidosilyl | en |
dc.title | Dichloro(methyl) silyl-substituted cyclopentadienyl titanium complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(97)00518-4 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(97)00518-4 | |
dc.relation.projectID | PB-92-0178-C (Ministerio de Educación y Cultura) | |
dc.relation.projectID | 042/95 (Universidad de Alcalá-UAH) | |
dc.relation.projectID | I + D 0034/94 (Comunidad de Madrid) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |