dc.contributor.author | Acebrón Moreno, Sergio | |
dc.contributor.author | Galakhov, Mikhail V. | |
dc.contributor.author | Gómez Sal, Pilar | |
dc.contributor.author | Martín Alonso, Avelino | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Vázquez de Miguel, Amelio | |
dc.date.accessioned | 2009-10-15T10:30:51Z | |
dc.date.available | 2009-10-15T10:30:51Z | |
dc.date.issued | 1999 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 1999, v. 580, p. 110-116 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4243 | |
dc.description.abstract | This paper reports the alkylation of the cyclopentadienyl imido tungsten complexes [WCp′(NtBu)Cl3] (Cp′=η5-C5H5, η5-C5Me5) with β-hydrogen containing alkyl groups to render halo alkyl and trialkyl complexes [WCp′(NtBu)Cl3−nRn] (R=Et, n-Pr). Thermal decomposition of the trialkyl compounds gives the alkylidene derivatives [WCp′(NtBu)(CHR)(CH2R)] (R=Me, Et) by α-hydrogen elimination. All of the compounds were characterized by NMR spectroscopy and the molecular structure of [W(η5-C5Me5)(NtBu)Et3] was determined by X-ray diffraction methods. | en |
dc.description.sponsorship | The authors acknowledge DGICYT (project PB97-0677) for financial support. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 1999 | en |
dc.subject | Alkyl | en |
dc.subject | Alkylidene | en |
dc.subject | Imido | en |
dc.subject | Tungsten | en |
dc.title | Alkyl and alkylidene imido cyclopentadienyl tungsten complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(98)01132-2 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(98)01132-2 | |
dc.relation.projectID | PB97-0677 (DGICYT) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |