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dc.contributor.authorAmor Chico, Francisco Javier 
dc.contributor.authorRoyo Gracia, Pascual 
dc.contributor.authorSpaniol, Thomas P.
dc.contributor.authorOkuda, Jun
dc.date.accessioned2009-10-06T10:02:42Z
dc.date.available2009-10-06T10:02:42Z
dc.date.issued2000
dc.identifier.bibliographicCitationJournal of Organometallic Chemistry, 2000, v.604, n.1, p.126-131en
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/10017/4207
dc.description.abstractMolybdenum and tungsten complexes M(η5-C5H4CH2-η-CH2)(CO)3 (M=Mo, W) containing the bidentate ethyl-functionalized cyclopentadienyl ligand C5H4CH2CH2 have been synthesized by the reaction of spiro[2.4]hepta-4,6-diene with M(CO)3L3 (M=Mo; L3=1,3,5-C6H3Me3; M=W; L=NCMe). Reaction of the more stable tungsten complex with C6H5ICl2 and HBF4 gave complexes of the type W(η5-C5H4CH2CH2Cl)(CO)3Cl, W(η5-C5H4CH2CH3)(CO)3Cl and W(η5-C5H4CH2CH3)(CO)3(FBF3), respectively. The crystal structure of the tungsten tricarbonyl complex W(η5-C5H4CH2-η-CH2)(CO)3 has been determined by X-ray crystal diffraction on a single crystal and shows a four-legged piano stool structure.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherElsevieren
dc.rights© Elsevier, 2000en
dc.subjectMolybdenumen
dc.subjectTungstenen
dc.subjectCyclopentadienyl-ethyl liganden
dc.titleChelated η5-cyclopentadienyl-η-ethyl complexes of molybdenum and tungsten; molecular structure of W(η5-C5H4CH2-η-CH2)(CO)3en
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCIENCIAes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaSCIENCEen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1016/S0022-328X(00)00218-7
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/S0022-328X(00)00218-7
dc.relation.projectIDPB97-0776 (Dirección General de Investigación Científica y Técnica)
dc.relation.projectIDE021/99 (Universidad de Alcalá)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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