dc.contributor.author | Amor Chico, Francisco Javier | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Spaniol, Thomas P. | |
dc.contributor.author | Okuda, Jun | |
dc.date.accessioned | 2009-10-06T10:02:42Z | |
dc.date.available | 2009-10-06T10:02:42Z | |
dc.date.issued | 2000 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 2000, v.604, n.1, p.126-131 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4207 | |
dc.description.abstract | Molybdenum and tungsten complexes M(η5-C5H4CH2-η-CH2)(CO)3 (M=Mo, W) containing the bidentate ethyl-functionalized cyclopentadienyl ligand C5H4CH2CH2 have been synthesized by the reaction of spiro[2.4]hepta-4,6-diene with M(CO)3L3 (M=Mo; L3=1,3,5-C6H3Me3; M=W; L=NCMe). Reaction of the more stable tungsten complex with C6H5ICl2 and HBF4 gave complexes of the type W(η5-C5H4CH2CH2Cl)(CO)3Cl, W(η5-C5H4CH2CH3)(CO)3Cl and W(η5-C5H4CH2CH3)(CO)3(FBF3), respectively. The crystal structure of the tungsten tricarbonyl complex W(η5-C5H4CH2-η-CH2)(CO)3 has been determined by X-ray crystal diffraction on a single crystal and shows a four-legged piano stool structure. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 2000 | en |
dc.subject | Molybdenum | en |
dc.subject | Tungsten | en |
dc.subject | Cyclopentadienyl-ethyl ligand | en |
dc.title | Chelated η5-cyclopentadienyl-η-ethyl complexes of molybdenum and tungsten; molecular structure of W(η5-C5H4CH2-η-CH2)(CO)3 | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0022-328X(00)00218-7 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0022-328X(00)00218-7 | |
dc.relation.projectID | PB97-0776 (Dirección General de Investigación Científica
y Técnica) | |
dc.relation.projectID | E021/99 (Universidad de Alcalá) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |