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Chelated η5-cyclopentadienyl-η-ethyl complexes of molybdenum and tungsten; molecular structure of W(η5-C5H4CH2-η-CH2)(CO)3

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Authors
Amor Chico, Francisco JavierUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; Spaniol, Thomas P.; Okuda, Jun
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4207
DOI: 10.1016/S0022-328X(00)00218-7
ISSN: 0022-328X
Publisher
Elsevier
Date
2000
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Journal of Organometallic Chemistry, 2000, v.604, n.1, p.126-131
Keywords
Molybdenum
Tungsten
Cyclopentadienyl-ethyl ligand
Project
PB97-0776 (Dirección General de Investigación Científica y Técnica)
E021/99 (Universidad de Alcalá)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0022-328X(00)00218-7
Rights
© Elsevier, 2000
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Molybdenum and tungsten complexes M(η5-C5H4CH2-η-CH2)(CO)3 (M=Mo, W) containing the bidentate ethyl-functionalized cyclopentadienyl ligand C5H4CH2CH2 have been synthesized by the reaction of spiro[2.4]hepta-4,6-diene with M(CO)3L3 (M=Mo; L3=1,3,5-C6H3Me3; M=W; L=NCMe). Reaction of the more stable tungsten complex with C6H5ICl2 and HBF4 gave complexes of the type W(η5-C5H4CH2CH2Cl)(CO)3Cl, W(η5-C5H4CH2CH3)(CO)3Cl and W(η5-C5H4CH2CH3)(CO)3(FBF3), respectively. The crystal structure of the tungsten tricarbonyl complex W(η5-C5H4CH2-η-CH2)(CO)3 has been determined by X-ray crystal diffraction on a single crystal and shows a four-legged piano stool structure.
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