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dc.contributor.authorCano Sierra, Jesús 
dc.contributor.authorSudupe Ormeño, María 
dc.contributor.authorRoyo Gracia, Pascual 
dc.contributor.authorGonzález Mosquera, Marta Elena 
dc.date.accessioned2009-10-05T10:53:20Z
dc.date.available2009-10-05T10:53:20Z
dc.date.issued2006
dc.identifier.bibliographicCitationAngewandte Chemie International Edition, 2006, v. 45, p. 7572-7574en
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10017/4199
dc.description.abstractIn summary, we have found experimental evidence to support a reaction pathway involving direct fluoride migration to the zirconium cation without previous transfer of C6F5. It is noteworthy that the opening of the silyl–amido bridge was not observed in the course of these activations. Experiments with other donor ligands are in progress to investigate the conditions under which the ion pairs 1 and 2 may follow different decomposition routes and the possible mechanisms of these reactions.en
dc.description.sponsorshipFinancial support by the Spanish MEC (project MAT2004-02614) and DGUI/CM (program S/0505/PPQ-0328) is acknowleged.en
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.publisherJohn Wiley & Sonsen
dc.rights(c) Wiley, 2006en
dc.subjectHomogeneous catalysisen
dc.subjectIon pairsen
dc.subjectPolymerizationen
dc.subjectReaction mechanismsen
dc.subjectZirconiumen
dc.titleEvidence of fluoride transfer from the anion of [Zr{C5H3[SiMe2(η1-NtBu)]2}]+[RB(C6F5)3]_ complexes to the zirconocenium cationen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaCienciaes_ES
dc.subject.ecienciaQuímica inorgánicaes_ES
dc.subject.ecienciaScienceen
dc.subject.ecienciaChemistry, inorganicen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Inorgánica
dc.relation.publisherversionhttp://dx.doi.org/10.1002/ange.200602694
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1002/ange.200602694
dc.relation.projectIDMAT2004-02614 (Ministerio de Educación y Ciencia-MEC)
dc.relation.projectIDS-0505/PPQ-0328 (Comunidad de Madrid)
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen


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