dc.contributor.author | Cano Sierra, Jesús | |
dc.contributor.author | Sudupe Ormeño, María | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | González Mosquera, Marta Elena | |
dc.date.accessioned | 2009-10-05T10:53:20Z | |
dc.date.available | 2009-10-05T10:53:20Z | |
dc.date.issued | 2006 | |
dc.identifier.bibliographicCitation | Angewandte Chemie International Edition, 2006, v. 45, p. 7572-7574 | en |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | http://hdl.handle.net/10017/4199 | |
dc.description.abstract | In summary, we have found experimental evidence to support a reaction pathway involving direct fluoride migration
to the zirconium cation without previous transfer of C6F5.
It is noteworthy that the opening of the silyl–amido bridge was not observed in the course of these activations. Experiments with other donor ligands are in progress to investigate the conditions under which the ion pairs 1 and 2 may follow different decomposition routes and the possible mechanisms of these reactions. | en |
dc.description.sponsorship | Financial support by the Spanish MEC (project MAT2004-02614)
and DGUI/CM (program S/0505/PPQ-0328) is acknowleged. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | John Wiley & Sons | en |
dc.rights | (c) Wiley, 2006 | en |
dc.subject | Homogeneous catalysis | en |
dc.subject | Ion pairs | en |
dc.subject | Polymerization | en |
dc.subject | Reaction mechanisms | en |
dc.subject | Zirconium | en |
dc.title | Evidence of fluoride transfer from the anion of
[Zr{C5H3[SiMe2(η1-NtBu)]2}]+[RB(C6F5)3]_
complexes to the zirconocenium cation | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1002/ange.200602694 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1002/ange.200602694 | |
dc.relation.projectID | MAT2004-02614 (Ministerio de Educación y Ciencia-MEC) | |
dc.relation.projectID | S-0505/PPQ-0328 (Comunidad de Madrid) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |