Carbon dioxide activation assisted by a bis(chlorodimethylsilyl)cyclopentadienyl titanium compound

Authors
Santamaría, David; Cano Sierra, JesúsUniversity of Alcalá Author; Royo Gracia, PascualUniversity of Alcalá Author; González Mosquera, Marta ElenaUniversity of Alcalá Author; Cuenca Agreda, Tomás; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4197
DOI: 10.1002/ange.200500716
ISSN: 1521-3757
Publisher
John Wiley & Sons
Date
2005
Affiliation
Universidad de Alcalá. Departamento de Química Inorgánica
Bibliographic citation
Angewandte Chemie, 2005, v. 44, p. 5828-5830
Keywords
Silicon
Titanium
Ab initio calculations
Carbon dioxide fixation
Project
MAT2004-02614 (Ministerio de Educación y Ciencia)
BQU2003-07281 (Ministerio de Ciencia y Tecnología)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1002/ange.200500716
Rights
© Wiley, 2005
Access rights
info:eu-repo/semantics/openAccess
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Abstract
A great deal of interest has focused on the role of metal ions as the active centers in the fixation of CO2 and its transformation. Activation of CO2 by hydroxo and oxo metal complexes to afford metal hydrogencarbonato and carbonato species, respectively, is related to the function of the carbonic anhydrase metalloenzyme, which catalyzes the physiologically important hydration of CO2 to hydrogencarbonate.
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