Synthesis of new conjugated mesomeric betaines from alkoxycarbonylazinium salts

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Authors
Valenciano Martínez, JesúsUniversity of Alcalá Author; Cuadro Palacios, Ana MaríaUniversity of Alcalá Author; Vaquero López, Juan JoséUniversity of Alcalá Author; García Navío, José LuisUniversity of Alcalá Author; Álvarez-Builla Gómez, JulioUniversity of Alcalá Author; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/4195
DOI: 10.1016/0040-4020(96)00662-X
ISSN: 0040-4020
Publisher
Elsevier
Date
1996
Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica
Teaching unit
Unidad docente Química Orgánica
Funders
Comisió Interdepartamental de Reçerca i Innovació Tecnológica
Bibliographic citation
Tetrahedron, 1996, v. 52, n. 34, p. 11349-11360
Keywords
Conjugated mesomeric betaines
Alkoxycarbonylazinium salts
Project
info:eu-repo/grantAgreement/CIRIT//QFN94-4619/ES
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0040-4020(96)00662-X
Rights
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Access rights
info:eu-repo/semantics/openAccess
Abstract
A new series of conjugated mesomeric betaines have been synthesized from the reaction of various aminoheterocycles with 2-methylthio-4-oxo-3-phenylpyrido[2,1-φ][1,2,4]triazinium iodide, itself prepared from 2-ethoxycarbonylpyridinium N-aminide. Some of the heterobetaines and salts obtained have been studied by 1H-NMR, and their structures have been confirmed by X-ray analysis. The crystal structures reveal unexpected complementary stabilizing interactions between some betaines and their salts.

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