dc.contributor.author | Sebastián Navas, Alfredo | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.contributor.author | Gómez Sal, Pilar | |
dc.contributor.author | Herdtweck, Eberhardt | |
dc.date.accessioned | 2009-10-02T11:04:44Z | |
dc.date.available | 2009-10-02T11:04:44Z | |
dc.date.issued | 2003 | |
dc.identifier.bibliographicCitation | Inorganica Chimica Acta, 2003, v. 350, p. 511-519 | en |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | http://hdl.handle.net/10017/4189 | |
dc.description.abstract | 2-(2-Methylbenz[e]indenyl)-2-cyclopentadienyl-propane [MeC13H8CMe2C5H5] (1) (MBICMe2Cp), was synthesized by reaction of LiMBI with 6,6-dimethylfulvene. The silyl derivatives [MeC13H8SiMeRCl] (R=Me 2, H 4) were isolated by reaction of 2-methylbenz[e]indene (LiMBI) with SiMeRCl2 and further reactions of 2 and 4 with NaCp afforded the silyl-bridged compounds [MeC13H8SiMeRC5H5] (R=Me 3, H 5). Metallation of 1 and 3 with 2 equiv. of LiBu gave the dilithium salts Li2[MeC13H7EMe2C5H4)] (E=C 6, Si 7) which were reacted with ZrCl4(THF)2 to obtain the ansa-metallocenes [Zr(MeC13H7EMe2C5H4)Cl2] (E=C 8, Si 9). A similar reaction of 5 with 2 equiv. of LiBu provided a mixture of the two diastereomers [Zr{MeC13H7SiMeBuC5H4}Cl2] (10a, 10b). Analogous metallation of [MeC13H8SiMe2(NH-t-Bu)] gave Li2[MeC13H7SiMe2(N-t-Bu)] which was used to prepare the amidosilyl derivatives [M{MeC13H7SiMe2η-(N-t-Bu)}Cl2] (M=Zr 11, Ti 12) by reaction with ZrCl4(THF)2 and TiCl3(THF)3 and further oxidation with PbCl2 (Ti). All of the new complexes were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of complexes 9 and 10a were studied by X-ray diffraction methods. | en |
dc.description.sponsorship | Financial support of our work by MCyT (Project MAT2001-1309) is gratefully acknowledged. A.S. is grateful to Repsol-YPF for a fellowship. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | (c) Elsevier, 2003 | en |
dc.subject | Ansa -Metallocenes | en |
dc.subject | Methylbenz[e ]indenyl silylamido | en |
dc.subject | Titanium | en |
dc.subject | Zirconium | en |
dc.title | Methylbenz[e]indenyl asymmetric ansa-metallocene and silylamido zirconium complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0020-1693(02)01521-9 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/S0020-1693(02)01521-9 | |
dc.relation.projectID | MAT2001-1309 (Ministerio de Ciencia y Tecnología) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |