dc.contributor.author | Cano Sierra, Jesús | |
dc.contributor.author | Sudupe Ormeño, María | |
dc.contributor.author | Royo Gracia, Pascual | |
dc.date.accessioned | 2009-10-01T10:00:34Z | |
dc.date.available | 2009-10-01T10:00:34Z | |
dc.date.issued | 2007 | |
dc.identifier.bibliographicCitation | Journal of Organometallic Chemistry, 2007, v.692, n.21, p.4448-4459 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/10017/4170 | |
dc.description.abstract | We present in this account the synthesis and recent developments of a new class of group 4 metal complexes with the tridentate di(silylamido)cyclopentadienyl ligand. These doubly silyl-bridged group 4 metal amido chelates are receiving increasing interest as they are efficient catalysts for ethene polymerization when activated with MAO despite generating 14-electron d0 cationic species free of the alkyl group required for the first insertion reaction in the polymerization process. | en |
dc.description.sponsorship | Programa Juan de la Cierva (Ministerio de Educación y Ciencia) | es_ES |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Elsevier | en |
dc.rights | © Elsevier, 2007 | |
dc.subject | Silylamido | en |
dc.subject | Cyclopentadienyl | en |
dc.subject | Titanium | en |
dc.subject | Zirconium | en |
dc.title | Synthesis and reactivity of di(silylamido)cyclopentadienyl titanium and zirconium complexes | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química inorgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, inorganic | es_ES |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Inorgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.jorganchem.2007.06.049 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/j.jorganchem.2007.06.049 | |
dc.relation.projectID | MAT2004-02614 (Ministerio de Educación y Ciencia) | |
dc.relation.projectID | S0505/PPQ-0328/COMAL-CM (Comunidad de Madrid) | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |