Encapsulation of a trinuclear silver(I) cluster by two imido-nitrido metalloligands [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]

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Authors
Martín Alonso, AvelinoUniversity of Alcalá Author; Martínez Espada, NoeliaUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Yélamos Sánchez, CarlosUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/39791
DOI: 10.1039/b704180b
ISSN: 1359-7345
Publisher
Royal Society of Chemistry
Date
2007-05-10
Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Teaching unit
Unidad docente Química Inorgánica
Funders
Ministerio de Educación y Ciencia
Comunidad de Madrid
Universidad de Alcalá
Bibliographic citation
Martin A, Martinez-Espada N, Mena M, Yelamos C. Encapsulation of a trinuclear silver(I) cluster by two imido-nitrido metalloligands [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]. Chemical Communications 2007(28):2983-2985.
Project
info:eu-repo/grantAgreement/AEI//CTQ2005-00238/ES/Complejos polinucleares de nitruros y óxidos metálicos
info:eu-repo/grantAgreement/CAICYT/Plan Nacional de I+D+i 2008-2011/CSD2006-00015/ES/Factoría de cristalización
Document type
info:eu-repo/semantics/article
Publisher's version
https://pubs.rsc.org/en/content/articlelanding/2007/CC/B704180B#!divAbstract
Rights
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
© Royal Society of Chemistry, 2007
Access rights
info:eu-repo/semantics/openAccess
Abstract
Treatment of the metalloligand [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] with silver(I) trifluoromethanesulfonate in different molar ratios gives the ionic compounds [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}(2)][O3SCF3] and [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] [O3SCF3] or the triangular silver cluster [(CF3SO2O)(3)Ag-3{(mu(3)-NH) Ti-3(3)(eta(5)-C5Me5)(3)(mu(3)-N)}(2)] in which each face is capped by a metalloligand.

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