Yttrium and Erbium Halide Complexes with [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] as a Neutral Tridentate Ligand

Authors
Caballo González, JorgeUniversity of Alcalá Author; García Castro, MaríaUniversity of Alcalá Author; Martín Alonso, AvelinoUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Pérez Redondo, AdriánUniversity of Alcalá Author; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38626
DOI: 10.1021/ic8010426
ISSN: 0020-1669
Date
2008-08-18
Affiliation
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Funders
Ministerio de Educación y Ciencia de España, Comunidad de Madrid, Universidad de Alcalá
Bibliographic citation
Inorganic Chemistry, 2008, v. 47, n. 16, p. 7077-7079
Project
CTQ2005-00238/BQU, CCG06-UAH/PPQ-0665, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© American Chemical Society, 2008
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Treatment of [{TiCp*(mu-NH)}(3)(mu(3)-N)] (1; Cp* = eta(5)-C5Me5) with yttrium and erbium halide complexes [MCl3(THF)(3.5)] and [MCpCl2(THF)(3)] (Cp = eta(5)-C5H5) gives cube-type adducts [Cl3M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] and [CPCl2M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}]. An analogous reaction of 1 with [{MCp2Cl}(2)] in toluene affords [Cp3M(mu-Cl)ClCpM{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] (M = Y, Er).
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