Yttrium and Erbium Halide Complexes with [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] as a Neutral Tridentate Ligand

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Authors
Caballo González, JorgeUniversity of Alcalá Author; García Castro, MaríaUniversity of Alcalá Author; Martín Alonso, AvelinoUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Pérez Redondo, AdriánUniversity of Alcalá Author; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38626
DOI: 10.1021/ic8010426
ISSN: 0020-1669
Date
2008-08-18
Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Teaching unit
Unidad docente Química Inorgánica
Funders
Ministerio de Educación y Ciencia
Comunidad de Madrid
Universidad de Alcalá
Bibliographic citation
Inorganic Chemistry, 2008, v. 47, n. 16, p. 7077-7079
Project
info:eu-repo/grantAgreement/CAICYT/Plan Nacional de I+D+i 2008-2011/CSD2006-00015/ES/Factoría de cristalización
info:eu-repo/grantAgreement/AEI//CTQ2005-00238/ES/Complejos polinucleares de nitruros y óxidos metálicos
info:eu-repo/grantAgreement/UAH//CCG06-UAH%2FPPQ-0665/ES/Diseño de nitruros metálicos moleculares precursores y modelos de materiales cerámicos
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© American Chemical Society, 2008
Access rights
info:eu-repo/semantics/openAccess
Abstract
Treatment of [{TiCp*(mu-NH)}(3)(mu(3)-N)] (1; Cp* = eta(5)-C5Me5) with yttrium and erbium halide complexes [MCl3(THF)(3.5)] and [MCpCl2(THF)(3)] (Cp = eta(5)-C5H5) gives cube-type adducts [Cl3M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] and [CPCl2M{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}]. An analogous reaction of 1 with [{MCp2Cl}(2)] in toluene affords [Cp3M(mu-Cl)ClCpM{(mu(3)-NH)(3)Ti3Cp*(3)(mu(3)-N)}] (M = Y, Er).

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