Electrophilic attack on trinuclear titanium imido-nitrido systems

Authors
Caballo González, JorgeUniversity of Alcalá Author; González Moreiras, MarianoUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Pérez Redondo, AdriánUniversity of Alcalá Author; Yélamos Sánchez, CarlosUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38586
DOI: 10.1039/C2DT30486D
ISSN: 1477-9226
Date
2012-05-28
Affiliation
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Funders
Ministerio de Educación y Ciencia de España, Comunidad de Madrid, Universidad de Alcalá
Bibliographic citation
Dalton Transactions, 2012, v. 41, n. 20, p. 6069-6071
Project
CTQ2008-00061/BQU, CCG10-UAH/PPQ-5935, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© The Royal Society of Chemistry, 2012
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Alkylation of [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] with MeOTf occurs at the imido ligands to produce the methylamido derivative [Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)(mu-NH)(2)(mu-NHMe)(OTf)] which readily rearranges to form the methylimido complex [Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)(mu-NH)(mu-NH2)(mu-NMe)(OTf)].
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