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dc.contributor.authorMartínez Espada, Noelia
dc.contributor.authorMena Montoro, Miguel
dc.contributor.authorGonzález Mosquera, Marta Elena
dc.contributor.authorPérez Redondo, Adrián
dc.contributor.authorYélamos Sánchez, Carlos
dc.date.accessioned2019-07-10T10:10:34Z
dc.date.available2019-07-10T10:10:34Z
dc.date.issued2010-12-27
dc.identifier.bibliographicCitationOrganometallics, 2010, v. 29, n. 24, p. 6732-6738en
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/10017/38547en
dc.description.abstractThe treatment of [ClCu{(mu(3) NH)(3)Ti-3(eta(5) C5Me5)(3)(mu(3) N)}] (2) with lithium cyclopentadienide in toluene at room temperature affords [(C5H5)Cu{(mu(3) NH)(3)Ti-3(eta(5) C5Me5)(3)(mu(3) N)}] (4) where the cyclopentadienyl ligand is bound to copper(l) in an eta(2) fashion The analogous reaction of 2 with lithium acetylides [Li(C equivalent to CR)] gives complexes [(RC equivalent to C)Cu{(mu(3) NH)(3) (eta(5) C5Me5)(3)(mu(3) N)}] (R = SiMe3 (5) Ph (6)) with terminal alkynyl ligands bound to copper Compound 6 is prepared in higher yield by the treatment of [{Ti(eta(5) C5Me5)(mu NH)}(3)(mu(3) N)] (1) with [Cu(C equivalent to CPh)] in toluene at room temperature The cyclopentadienyl derivative 4 decomposes in solution to generate the edge linked double cube nitrido complex [{Cu(mu(4) N)(mu(3) NH)(2)Ti-3(eta(5) C5Me5)(3)(mu(3) N)}(2)] (3) via C5H6 elimination However solutions of the alkynyl derivatives 5 and 6 lead to copper(I) acetylide bridged double cube complexes [{Cu(mu 1 kappa C-1 2 kappa C-1 C equivalent to CR)Cu(mu(4) N)(mu(3) NH)(2)Ti-3(eta(5) C5Me5)(3)(mu(3) N)}(2)] (R = SiMe3 (7) Ph (8)) along with 1 and RC equivalent to CH The X ray crystal structures of 4 5 7 and 8 have been determineden
dc.description.sponsorshipMinisterio de Educación y Ciencia de Españaes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© American Chemical Society, 2010en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleCyclopentadienyl and Alkynyl Copper(I) Derivatives with the [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] Metalloliganden
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaChemistryen
dc.subject.ecienciaQuímicaes_ES
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
dc.date.updated2019-07-10T10:06:50Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/om100824qen
dc.relation.projectIDCTQ2008-00061/BQU, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010 CSD2006-00015es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000010483en
dc.identifier.publicationtitleOrganometallicsen
dc.identifier.publicationvolume29
dc.identifier.publicationlastpage6738
dc.identifier.publicationissue24
dc.identifier.publicationfirstpage6732


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