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Mercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systems

dc.contributor.authorMartín Alonso, Avelino 
dc.contributor.authorMartínez Espada, Noelia 
dc.contributor.authorMena Montoro, Miguel 
dc.contributor.authorGonzález Mosquera, Marta Elena 
dc.contributor.authorPérez Redondo, Adrián 
dc.contributor.authorYélamos Sánchez, Carlos 
dc.date.accessioned2019-07-08T09:15:36Z
dc.date.available2019-07-08T09:15:36Z
dc.date.issued2008-11-11
dc.identifier.bibliographicCitationChemical Communications, 2008, n. 48, p. 6561-6563en
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/10017/38492en
dc.description.abstractThe imido - nitrido complex [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl) amide reagents to afford [M-2{(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti-3(eta(5)-C5Me5)(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.en
dc.description.sponsorshipMinisterio de Educación y Ciencia de España, Comunidad de Madrid, Universidad de Alcaláes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© The Royal Society of Chemistry, 2008en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleMercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systemsen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
dc.date.updated2019-07-08T09:14:23Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1039/B814982H, Communicationen
dc.relation.projectIDCTQ2005-00238, CCG06-UAH/PPQ-0665, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000010513en
dc.identifier.publicationtitleChemical Communicationsen
dc.identifier.publicationlastpage6563
dc.identifier.publicationissue48
dc.identifier.publicationfirstpage6561


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