Mercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systems
Authors
Martín Alonso, Avelino; Martínez Espada, Noelia; Mena Montoro, Miguel; González Mosquera, Marta Elena; Pérez Redondo, Adrián; [et al.]Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38492DOI: 10.1039/B814982H, Communication
ISSN: 1359-7345
Date
2008-11-11Funders
Ministerio de Educación y Ciencia de España, Comunidad de Madrid, Universidad de Alcalá
Bibliographic citation
Chemical Communications, 2008, n. 48, p. 6561-6563
Project
CTQ2005-00238, CCG06-UAH/PPQ-0665, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© The Royal Society of Chemistry, 2008
Access rights
info:eu-repo/semantics/openAccess
Abstract
The imido - nitrido complex [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl) amide reagents to afford [M-2{(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti-3(eta(5)-C5Me5)(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.
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