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Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes

dc.contributor.authorGreño Ocariz, Maider 
dc.contributor.authorMena Montoro, Miguel 
dc.contributor.authorPérez Redondo, Adrián 
dc.contributor.authorYélamos Sánchez, Carlos 
dc.date.accessioned2019-07-04T07:25:14Z
dc.date.available2019-07-04T07:25:14Z
dc.date.issued2017-04-28
dc.identifier.bibliographicCitationDalton Transactions, 2017, v. 46, n. 16, p. 5138-5142en
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/10017/38446en
dc.description.abstractMono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine‒borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with Zr···H-B interactions which readily undergo β-hydride elimination to give hydride functions.en
dc.description.sponsorshipMinisterio de Economía y Competitividad de España, Universidad de Alcaláes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© The Royal Society of Chemistry, 2017en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleIsolable zirconium hydride species in the reaction of amido complexes with amine-boranesen
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
dc.date.updated2019-07-04T07:23:56Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1039/C7DT00857Ken
dc.relation.projectIDCCG2015/EXP-026 (Universidad de Alcalá)es_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO//CTQ2013-44625-R/ES/ACTIVACION Y FUNCIONALIZACION DE DINITROGENO EN COMPLEJOS POLIMETALICOS COMO ALTERNATIVA AL PROCESO HABER-BOSCH EN LA PRODUCCION DE AMONIACO/es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000025763en
dc.identifier.publicationtitleDalton Transactionsen
dc.identifier.publicationvolume46
dc.identifier.publicationlastpage5142
dc.identifier.publicationissue16
dc.identifier.publicationfirstpage5138


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