Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes

Authors
Greño Ocariz, MaiderUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Pérez Redondo, AdriánUniversity of Alcalá Author; Yélamos Sánchez, CarlosUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38446
DOI: 10.1039/C7DT00857K
ISSN: 1477-9226
Date
2017-04-28
Affiliation
Universidad de Alcalá. Departamento de Química Analítica, Química Física e Ingeniería Química; Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Funders
Ministerio de Economía y Competitividad de España, Universidad de Alcalá
Bibliographic citation
Dalton Transactions, 2017, v. 46, n. 16, p. 5138-5142
Project
CCG2015/EXP-026 (Universidad de Alcalá)
info:eu-repo/grantAgreement/MINECO//CTQ2013-44625-R/ES/ACTIVACION Y FUNCIONALIZACION DE DINITROGENO EN COMPLEJOS POLIMETALICOS COMO ALTERNATIVA AL PROCESO HABER-BOSCH EN LA PRODUCCION DE AMONIACO/
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© The Royal Society of Chemistry, 2017
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine‒borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with Zr···H-B interactions which readily undergo β-hydride elimination to give hydride functions.
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