Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

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Authors
Caballo González, JorgeUniversity of Alcalá Author; González Moreiras, MarianoUniversity of Alcalá Author; Greño Ocariz, MaiderUniversity of Alcalá Author; Mena Montoro, MiguelUniversity of Alcalá Author; Pérez Redondo, AdriánUniversity of Alcalá Author; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38432
DOI: 10.1021/ic5015972
ISSN: 0020-1669
Date
2014-09-02
Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Teaching unit
Unidad docente Química Inorgánica
Funders
Ministerio de Ciencia e Innovación
Universidad de Alcalá
Comisión Asesora de Investigación Científica y Técnica
Bibliographic citation
Inorganic Chemistry, 2014, v. 53, n. 17, p. 8851-8853
Project
info:eu-repo/grantAgreement/MICINN//CTQ2008-00061%2FBQU/ES/Síntesis y reactividad de nitruros y óxidos metálicos moleculares
info:eu-repo/grantAgreement/UAH//GC2013-002/ES
info:eu-repo/grantAgreement/CAICYT/Plan Nacional de I+D+i 2008-2011/CSD2006-00015/ES/Factoría de cristalización
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© American Chemical Society, 2014
Access rights
info:eu-repo/semantics/openAccess
Abstract
The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].

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