Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
Authors
Caballo González, Jorge; González Moreiras, Mariano; Greño Ocariz, Maider; Mena Montoro, Miguel; Pérez Redondo, Adrián; [et al.]Identifiers
Permanent link (URI): http://hdl.handle.net/10017/38432DOI: 10.1021/ic5015972
ISSN: 0020-1669
Date
2014-09-02Funders
Ministerio de Ciencia e Innovación de España, Universidad de Alcalá, Ministerio de Educación y Ciencia de España
Bibliographic citation
Inorganic Chemistry, 2014, v. 53, n. 17, p. 8851-8853
Project
CTQ2008-00061/BQU, UAHGC2013-002, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© American Chemical Society, 2014
Access rights
info:eu-repo/semantics/openAccess
Abstract
The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].
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