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dc.contributor.authorCaballo González, Jorge 
dc.contributor.authorCarbó, Jorge J.
dc.contributor.authorMena Montoro, Miguel 
dc.contributor.authorPérez Redondo, Adrián 
dc.contributor.authorPoblet Rius, Josep María
dc.contributor.authorYélamos Sánchez, Carlos 
dc.date.accessioned2019-07-02T10:34:14Z
dc.date.available2019-07-02T10:34:14Z
dc.date.issued2013-05-20
dc.identifier.bibliographicCitationInorganic Chemistry, 2013, v. 52, n. 10, p. 6103-6109en
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/10017/38387en
dc.description.abstractTreatment of [Cl3Y{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(/mu(3)-N)}] With [K(C5Me5)] in toluene gives Clo Meio and the paramagnetic [K(mu-Cl)(3)Y{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] (3) derivative. Crystallization of 3 in pyridine affords the potassium-free [Cl-2(py)(2)Y{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] (4) complex. Whereas the reaction of 3 with 1 equiv of 18-crown-6 leads to the molecular complex [(18-crown-6)K(mu-Cl)(3)Y{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] (5), the analogous treatment of 3 with cryptand-222 affords the ion pair [K(crypt-222)][Cl3Y{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] (6). The X-ray crystal structures of 4, 5, and 6 have been determined. Density functional theory (DFT) calculations have elucidated the electronic structure of these species, which should be regarded as containing trivalent Y bonded to the {(mu(3)-NH)(3)Ti-3(eta(5)-Me-5)(3)(mu(3)-N)) metalloligandradical anion.en
dc.description.sponsorshipMinisterio de Ciencia e Innovación de España, Comunidad de Madrid, Universidad de Alcalá, Generalitat de Catalunya, Ministerio de Educación y Ciencia de Españaes_ES
dc.format.mimetypeapplication/pdfen
dc.language.isoengen
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)en
dc.rights© American Chemical Society, 2013en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.titleRedox-Active Behavior of the [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)] Metalloliganden
dc.typeinfo:eu-repo/semantics/articleen
dc.subject.ecienciaQuímicaes_ES
dc.subject.ecienciaChemistryen
dc.contributor.affiliationUniversidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
dc.date.updated2019-07-02T10:32:24Z
dc.type.versioninfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/ic400463aen
dc.relation.projectIDCTQ2008-00061/BQU, CTQ2011-0 29054-C02-01/BQU, CCG10-UAH/PPQ-5935, 2009SGR-00462, XRQTC, "Factoría de Cristalización" CONSOLIDER-INGENIO 2010en
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessen
dc.identifier.uxxiAR/0000017874en
dc.identifier.publicationtitleInorganic Chemistryen
dc.identifier.publicationvolume52
dc.identifier.publicationlastpage6109
dc.identifier.publicationissue10
dc.identifier.publicationfirstpage6103


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