Azinium-N-(2'-azinyl)aminides: synthesis, structure and reactivity

Authors
Carceller Martí, Rosa; García Navío, José LuisUniversity of Alcalá Author; Izquierdo Ceinos, Ma Luisa; Álvarez-Builla Gómez, JulioUniversity of Alcalá Author; Fajardo, Mariano; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/3669
DOI: 10.1016/S0040-4020(01)90411-9
ISSN: 0040-4020
Publisher
Pergamon
Date
1994
Affiliation
Universidad de Alcalá. Departamento de Farmacología
Bibliographic citation
Tetrahedron, 1994, v. 50, n. 17, p. 4995-5012
Keywords
Salts
Betaines
Ylides
Project
PB90-0284 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/S0040-4020(01)90411-9
Rights
(c) Elsevier Science, 1994
Access rights
info:eu-repo/semantics/openAccess
Share
 
Abstract
Several azinium-N-(2'-azinyl)aminides are reported. The structure of pyridinium-N-(2'-pyridyl)aminide has been studied, both in solution and in crystalline state, and results have been compared. In non-polar solvents, the aminides present a planar conformation stabilized by an intramolecular hydrogen bond. The reactivity toward electrophiles confirms the structural data, producing either N- or C- substitutions under mild conditions.
Files in this item
Collections