Crystal structure of μ-oxido-1,1'κ2O:O-bis{tetra-μ-oxido-1:2κ2O:O;1:3κ2O:O;2:3κ4O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/35840DOI: 10.1107/S2056989015004041
ISSN: 2056-9890
Date
2015-03-21Funders
Comisión Asesora de Investigación Científica y Técnica
Bibliographic citation
Acta Crystallographica Section E (Crystallographic Communications), 2015, v. 71, n. 4, p. 97-97
Keywords
crystal structure
titanium oxide
pentamethylcyclopentadienyl ligand
organometallic
Project
info:eu-repo/grantAgreement/CAICYT/Plan Nacional de I+D+i 2008-2011/CSD2006-00015/ES/FACTORÍA DE CRISTALIZACIÓN
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Rights
Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
Access rights
info:eu-repo/semantics/openAccess
Abstract
The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-coordination fashion, while three bridging O atoms fill the other three sites.
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