Determination of nanogram microparticles from explosives after real open-air explosions by confocal Raman microscopy

Abstract

Explosives are increasingly being used for terrorist attacks to cause devastating explosions. The detection of their post-blast residues after an explosion is a high challenge, which has been barely investigated, particularly using spectroscopic techniques. In this research, a novel methodology using confocal Raman microscopy has been developed for the analysis of post-blast residues from ten open-air explosions caused by ten different explosives (TNT, RDX, PETN, TATP, HMTD, dynamite, black powder, ANFO, chloratite, and ammonal) commonly used in improvised explosive devices. The methodology for the determination of post-blast particles from explosives consisted of examining the samples surfaces with both the naked eye, first, and microscopically (10x and 50x), immediately afterward; and finally, analysing the selected residues by confocal Raman spectroscopy in order to identify the post-blast particles from explosives. Interestingly, confocal Raman microscopy has demonstrated to be highly suitable to rapidly, selectively and non-invasively analyse post-blast microscopic particles from explosives up to the nanogram range.