dc.contributor.author | Heras Muñoz, María Amor de las | |
dc.contributor.author | Vaquero López, Juan J. | |
dc.contributor.author | García Navío, José Luis | |
dc.contributor.author | Álvarez-Builla Gómez, Julio | |
dc.date.accessioned | 2009-05-11T12:32:07Z | |
dc.date.available | 2009-05-11T12:32:07Z | |
dc.date.issued | 1996 | |
dc.identifier.bibliographicCitation | Tetrahedron, 1996, v. 52, n. 45, p. 14297-14310 | en |
dc.identifier.issn | 0040-4020 | |
dc.identifier.uri | http://hdl.handle.net/10017/2792 | |
dc.description.abstract | A new method for the synthesis of selective acylating agents is described from the reaction of carboxylic acids with 3-methyl-1-methylamino-3H-imidazol-1-ium salts in the presence of appropriate coupling reagents. The amides and bis-amides thus prepared reacted selectively with organometallics to afford ketones and diketones and with DIBALH to give aldehydes and dialdehydes in high yields. | en |
dc.description.sponsorship | The authors acknowledge the Comisió Interdepartamental de Recerςa i Innovació Tecnológica (CIRIT, project QFN94-4619) for financial support and the Ministerio de Educaci6n y Ciencia for a studentship (M.A.H.). | en |
dc.description.sponsorship | Comissió Interdepartamental de Recerca i Innovació | cat |
dc.format.mimetype | application/pdf | en |
dc.language.iso | eng | en |
dc.publisher | Pergamon | en |
dc.rights | (c) Elsevier, 1996 | en |
dc.subject | Ketones | en |
dc.subject | Chemistry | en |
dc.subject | Chemistry, Organic | en |
dc.subject | Imidazole derivative | en |
dc.subject | Article | en |
dc.subject | Drug synthesis | en |
dc.subject | Priority journal | en |
dc.subject | Reaction analysis | en |
dc.subject | Technique | en |
dc.title | Synthesis of carbonyl and dicarbonyl compounds from organometallic reagents and N-imidazolium-N-methyl amides and bis-amides | en |
dc.type | info:eu-repo/semantics/article | en |
dc.subject.eciencia | Ciencia | es_ES |
dc.subject.eciencia | Química orgánica | es_ES |
dc.subject.eciencia | Science | en |
dc.subject.eciencia | Chemistry, organic | en |
dc.contributor.affiliation | Universidad de Alcalá. Departamento de Química Orgánica | |
dc.relation.publisherversion | http://dx.doi.org/10.1016/0040-4020(96)00882-4 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1016/0040-4020(96)00882-4 | |
dc.relation.projectID | info:eu-repo/grantAgreement/CIRIT//QFN94-4619/ES | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | en |