Synthesis of aldehydes from acyl chlorides via 1-(acylmethylamino)-3-methylimidazolium salts

Authors
Heras Muñoz, María Amor de lasUniversity of Alcalá Author; Vaquero López, Juan J.; García Navío, José LuisUniversity of Alcalá Author; Álvarez-Builla Gómez, JulioUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/2790
DOI: 10.1016/0040-4039(94)02284-I
ISSN: 0040-4039
Publisher
Pergamon
Date
1995
Affiliation
Universidad de Alcalá. Departamento de Química Orgánica
Funders
The authors are grateful for grant (MAH) from Ministerio de Educación y Ciencia and financial support from Comisión Interministerial de Ciencia y Tecnología (CICYT) through the project PB90-0284
Bibliographic citation
Tetrahedron Letters, 1995, v. 36, n. 3, p. 455-458
Keywords
Palladium-catalyzed reaction
Tributylin hydride
Carboxylic-acids
Reduction
Tetrahydroborate
Route
Chemistry, Organic
Project
PB90-0284 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0040-4039(94)02284-I
Rights
(c) Elsevier, 1995
Access rights
info:eu-repo/semantics/openAccess
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Abstract
The reaction of acyl chlorides with 1-amino-3-methylimidazolium salts, followed by N-methylation of the resulting H-aminides, afforded 1-(acylmethylamino)-3-methylimidazolium salts which, upon treatment with DIBALHgave aldehydes in good yields. A nalogously, dialdehydes were obtained from the corresponding bis-salts.
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