Synthesis of aldehydes from acyl chlorides via 1-(acylmethylamino)-3-methylimidazolium salts

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Authors
Heras Muñoz, María Amor de lasUniversity of Alcalá Author; Vaquero López, Juan JoséUniversity of Alcalá Author; García Navío, José LuisUniversity of Alcalá Author; Álvarez-Builla Gómez, JulioUniversity of Alcalá Author
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/2790
DOI: 10.1016/0040-4039(94)02284-I
ISSN: 0040-4039
Publisher
Pergamon
Date
1995
Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica
Teaching unit
Unidad docente Química Orgánica
Funders
The authors are grateful for grant (MAH) from Ministerio de Educación y Ciencia and financial support from Comisión Interministerial de Ciencia y Tecnología (CICYT) through the project PB90-0284
Bibliographic citation
Tetrahedron Letters, 1995, v. 36, n. 3, p. 455-458
Keywords
Palladium-catalyzed reaction
Tributylin hydride
Carboxylic-acids
Reduction
Tetrahydroborate
Route
Chemistry, Organic
Project
PB90-0284 (Comisión Interministerial de Ciencia y Tecnología-CICYT)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0040-4039(94)02284-I
Rights
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Access rights
info:eu-repo/semantics/openAccess
Abstract
The reaction of acyl chlorides with 1-amino-3-methylimidazolium salts, followed by N-methylation of the resulting H-aminides, afforded 1-(acylmethylamino)-3-methylimidazolium salts which, upon treatment with DIBALHgave aldehydes in good yields. A nalogously, dialdehydes were obtained from the corresponding bis-salts.

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