Reaction of imines with N-iodosuccinimide (NIS): unexpected formation of stable 1 : 1 complexes

Authors
Castellote Álvaro, María IsabelUniversity of Alcalá Author; Morón Galán, MaríaUniversity of Alcalá Author; Burgos García, CarolinaUniversity of Alcalá Author; Álvarez-Builla Gómez, JulioUniversity of Alcalá Author; Martín Alonso, AvelinoUniversity of Alcalá Author; [et al.]
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/2683
DOI: 10.1039/B615183C
ISSN: 1359-7345
Publisher
Royal Society of Chemistry
Date
2007
Affiliation
Universidad de Alcalá. Departamento de Química Orgánica
Funders
Financial support from the Spanish Ministerio de Educación y Ciencia (project CTQ2005/011060), Comunidad de Madrid (CAM) and Universidad de Alcalá (UAH) (project CAM/UAH- 2005/044) and grant (M-M.) from CAM-UAH is gratefully acknowledged
Bibliographic citation
Chemical communications, 2007, v. 12, p. 1281-1283
Keywords
Halogen
Bonds
Chemistry, Multidisciplinary
Project
CTQ2005/011060 (Ministerio de Educación y Ciencia)
CAM/UAH-2005/044(Comunidad de Madrid)
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1039/B615183C
Rights
(c) The Royal Society of Chemistry, 2007
Access rights
info:eu-repo/semantics/openAccess
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Abstract
Imines react with N-iodosuccinimide (NIS) to afford unexpected 1 : 1 complexes and the structure of one of these was determined by single-crystal X-ray diffraction; the reaction seems to be very general for substituted cyclic imines with solid stable complexes obtained in high yields; this is the first reported example of a halogen bonding interaction involving the CLN bond and NIS
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