N-(pyridylmethyl)azinium salts: precursors of pyridyl-stabilized azinium N-ylides
Authors
Agejas Chicharro, Francisco Javier; Cuadro Palacios, Ana María; Pastor Maeso, Manuel; Vaquero López, Juan J.; García Navío, José Luis; [et al.]Identifiers
Permanent link (URI): http://hdl.handle.net/10017/2609DOI: 10.1016/0040-4020(95)00798-D
ISSN: 0040-4020
Publisher
Pergamon
Date
1995Funders
Ministerio de Educación y Ciencia
Comisión Interministerial de Ciencia y Tecnología
Bibliographic citation
Tetrahedron, 1995, v.51, n.45, p.12425-12438
Keywords
Primary amino-groups
Benzimidazole derivatives
Mesomeric betaines
Chemistry, Organic
Project
info:eu-repo/grantAgreement/CICYT//PB90-0284/ES//
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/publishedVersion
Publisher's version
http://dx.doi.org/10.1016/0040-4020(95)00798-DRights
© Elsevier, 1995
Access rights
info:eu-repo/semantics/openAccess
Abstract
A series of new N-(pyridylmethyl)azinium salts have been synthesized from 2, 4, 6-triphenylpyrylium tetrafluoroborate. Generation of azinium N-ylides in the presence of base, has been proved by reactions with electrophiles, such as carbon disulphide, phenyl isothiocyanate and with acetylene dipolarophiles.
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