N-phenanthroline glycosylamines: synthesis and copper(II) complexes

Autores
Duskova, KaterinaAutor Universidad de Alcalá; Gude Rodríguez, LourdesAutor Universidad de Alcalá; Arias Pérez, María SelmaAutor Universidad de Alcalá
Identificadores
Enlace permanente (URI): http://hdl.handle.net/10017/20844
DOI: 10.1016/j.tet.2013.12.044
ISSN: 0040-4020
Editor
Elsevier
Fecha de publicación
2014
Filiación
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica. Unidad docente Química Orgánica
Patrocinadores
This research has received funding from the MICINN (project CTQ2011-26822), the MINECO (project CTQ2012-32711) and the European Community's Seventh Framework Programme ([FP7/2007-2013, under grant agreement 248638, to L.G. and K.D.]). We thank C. García for her collaboration in the synthesis of the Cu(II) complexes.
Cita bibliográfica
Tetrahedron, v. 70, n. 5, p. 1071-1076
Palabras clave
Glycosylamines
N-Glycosylation reactions
Phenanthroline derivatives
Copper(II) complexes
Proyectos
info:eu-repo/grantAgreement/EC/FP7/2007-2013/248638
CTQ2012-32711 (Ministerio de Economía y Competitividad)
CTQ2011-26822 (Ministerio de Ciencia e Innovación)
Tipo de documento
info:eu-repo/semantics/article
Versión
info:eu-repo/semantics/acceptedVersion
Versión del editor
http://dx.doi.org/10.1016/j.tet.2013.12.044
Derechos
(c) Elsevier, 2014
Derechos de acceso
info:eu-repo/semantics/openAccess
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Resumen
A series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes having a 2:1 mole ratio of the bidentate ligand phenanthroline N-glycoside and the metal were also prepared.
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