%0 Journal Article 
%A Otero Montero, Antonio
%A Royo Gracia, Pascual
%T Pentachlorophenyl-arsenic, pentachlorophenyl-antimony and pentachlorophenyl-bismuth compounds
%D 1979
%@ 0022-328X
%U http://hdl.handle.net/10017/4816
%X (C6Cl5)3Sb and (C6Cl5)3Bi have been isolated from SbCl3 or BiCl3 and C6Cl5Li. AsCl3 gives only (C6Cl5)2AsCl even with a large excess of C6Cl5Li. Treatment of (C6Cl5)3Sb with halogens gives (C6Cl5)3SbX2 (X=Cl, Br). Br2 does not react with (C6Cl5)2AsCl whereas Cl2 gives an intractable residue which is rapidly hydrolysed to [(C6Cl5)2As]2O. Treatment of (C6Cl5)3Bi with halogens cleaves the C-Bi bonds to give C6Cl5X and unidentified oxohalobismuth(III) derivatives.
%K Arsenic
%K Antimony
%K Bismuth
%K Ciencia
%K Química inorgánica
%K Science
%K Chemistry, inorganic
%~ Biblioteca Universidad de Alcala