%0 Journal Article 
%A Avilés, T.
%A Barroso Parla, Francisca
%A Royo Gracia, Pascual
%T New neutral and cationic cyclopentadienylcobalt complexes
%D 1987
%@ 0022-328X
%U http://hdl.handle.net/10017/4664
%X The treatment of the aquocation [Co(η3-2-MeC3H4)(η5-C5H5)(H2O]+ with neutral and anionic ligands gives new cobalt complexes containing cations [Co(η3-2-MeC3H4)(η5-C5H5)L]n+, n = 0; L = CN, CH3COO, CF3COO and n = 1; L = P(p-MePh)3, NCEt, NCPh, CNCy, dppm and [{Co(η3-2-MeC3H4)(η5-C5H5)}2 (μ-L-L)]2+, L-L = bipy, dppm. The neutral cyano complex reacts with various electrophiles to give cationic isocyanide complexes containing the cation [Co(η3-2-MeC3H4)(η5-C5H5)(CNR)]+, which have been isolated in low yields. Chemical behaviour and structural implications of IR and 1H and 13C NMR spectra are discussed.
%K Cyclopentadienylcobalt complexes
%K Ciencia
%K Química inorgánica
%K Science
%K Chemistry, inorganic
%~ Biblioteca Universidad de Alcala