%0 Journal Article 
%A Blom, R.
%A Rypdal, K.
%A Mena Montoro, Miguel
%A Royo Gracia, Pascual
%A Serrano Roche, Ricardo
%T The molecular structure of Me3TiCp* in the gas phase
%D 1990
%@ 0022-328X
%U http://hdl.handle.net/10017/4633
%X The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm.
%K Gas phase electron diffraction
%K GED
%K Methyl groups
%K Ciencia
%K Química inorgánica
%K Science
%K Chemistry, inorganic
%~ Biblioteca Universidad de Alcala